Bio-detergente derivado de aceite usado de fritura

Alfonso Jesús Torres Ortega; Nelly Morales Pedraza

doi:10.22490/25394088.588

Vol. 5 (2011)

Published 2011-04-13

license

When the Publicaciones e Investigaciones Journal receives an original study or article from its author(s), whether by email, postal service, or the platforms available for said purpose, know that it may be published in physical or electronic formats in national or international archives, databases, or SIRES. As such, Publications and Research authorizes the reproduction and citation of said material, provided that the description of information is carried out in conformity with bibliographic norms, and mention the corresponding names, authors, article, issue, and pages. Publications and Research, in advance, expresses that the information, concepts, and methods are the responsibility of the author(s). As such, the UNAD does not have any influence whatsoever over that expressed in the manuscript.

Original article

Bio-Detergent oil derivative used frying

DOI: https://doi.org/10.22490/25394088.588

Alfonso Jesús Torres Ortega Universidad de La Salle. Bogotá

Nelly Morales Pedraza Universidad Nacional Abierta y a Distancia

PDF (Spanish)

Abstract
References

Currently, the global trend towards sustainable development for environmental friendly products such as biosurfactants shows an excellent performance. Anionic surface active agents can be produced from renewable natural raw materials such as vegetable oils mainly derived from palm oil. Methyl ester sulfonate is an active component of highly biodegradable detergents, one advantage compared with detergents derived from petrochemicals which generate a high pollutant load. This paper proposes the study of sulfonation with sulfur trioxide of esters derived from waste cooking oil which main component is palm oil. The falling film reactor allows determining the conditions of the process at pilot scale. The experimentation allowed an enhancement of empirical equations in the equipment implemented for this purpose and to determine some physicochemical properties. The comparison obtained for this same process with petrochemicals compounds indicates that the model could be applied to any film sulfonation but adjusting the parameters and specific conditions, such as the physicochemical properties of the compounds used, since the sulfonation process described in this work is one of the more complicated cases. The technological development presented here seeks to contribute with the industrial needs to promote green chemical industry for the production of biosurfactant from waste frying oil.

keywords: detergent, sulfonation, methyl ester, modeling, palm oil.

Mingorance F. (2007), Producción de aceite de palma en Colombia- Belgica / Europa. “Acercamiento desde una perspectiva de derechos humanos”.

Ullmann F. 1985. Ullmann’s Encyclopedia of Industrial Chemistry. 5th edition. VCH Verlagsgescllchaftmbh, A14, A25.

Choo Y. M., CheahK.Y., Ma.A.N., Halim A., Ong A. S. H., Conversion its mof Crude palm kernel oil into its methyl esters on a pilot plant scale. Proceedings of the 1990.AOCS: World Conference on Oleochemicals into the 21st Century, Edited by Thhhomas H. Apple White. Kuala Lumpur, Malaysia, 292-295.

Lim, W.H., Ahmad, S. (2001). Surface tension, foaming and detergency properties of mixed alphasulphonated methyl esters derived from palm stearin with some commercial surfactants. Journal of Oil Palm Research, 13(1): 75–83.

Drozd, J.C. (1990). Use of sulfonated methyl esters in household cleaning products. Proceedings of the 1990 AOCS: World Conference on Oleochemicals into the 21st Century, Edited by Thomas H. Applewhite. Kuala Lumpur, Malaysia, 256–268.

Torres, J.A., Narváez, P.C., Sánchez, C.F.J., Ponce de leon Q.L.F. (2005). Obtención de estearato de metilo derivado de la estearina hidrogenada derivada del aceite de palma. Revista Publicaciones e Investigación de laUNAD, 4(2). 150-162.

Knaggs, E. (2004). Comment on “Optimization of the linear alkyl benzene sulfonation process for surfactant manufacture” and “Sulfonation technology for anionic surfactant manufacture”: Falling Film SO3 Sulfonation – Laminar or Turbulent Flow Controversy. Organic Process Research and Development, 8(6): 1079–1080.

Stein W., & Baumann H., (1975). A sulfonated fatty acid sand esters: manufacturing process, properties, and applications. JAOCS, 52: 323 – 329.

Inagaki T. (1990).Development of a-sulf o fatty acid esters. Proccedings of the 1990. AOCS: World Conference on Oleochemicals into the 21st Century, Edited by Thomas H. Applewhite. Kuala Lumpur, Malaysia, 269.

Ismail Z., Ahmad S. (1997). Greentech Engineering SDN, Palm-based anionic surfactants. PORIM Information Series No 48.

Lim W. H., Ho S. G., (1999). Properties of mixed alpha sulfonated methyl ester derived from palm stearin and polyoxyethylene sorbitan monoester in diluted solution. Proceedings of 1999 PORIM International Palm Oil Congress: Emerging Technologies and Opportunities in the Next Millennium.

Kuala Lumpur, Malaysia, 161-176.

Ahmad S., Siwayanan P., Abd Murad Z., Abd Aziz H., Seng Soi H., (2007). Beyond Biodiesel, Methyl Esters as the route for the production of Surfactants feedstock. INFORM, 18: 216-220.

Satsuki, T. (1994). Methyl ester sulfonates: A surfactantant based on natural fats. Lion Corporation, Fabric Care Research Labs. In: Proceedings of the 3rd World Conference on Detergents: Global Perspectivas. Editor: Arno Cahn. AOCS Press. New York, 135–140.

Freedman B.,Pryde E. H., Mounts T. L., (1984). Variables affecting the yields of fatty from transesterified vegetable oils. Journal of American Oil chemist Society, Vol: 61, No: 10, pág. 1638 – 1643.

Narváez R. P. C., Torres O. J. A., Sánchez C. F. J., Ponce de león Q. L. F., (2005). Determinación por cromatografía de gases de alquil ésteres (metilo y etilo) de ácidos grasos. Revista Publicaciones e Investigación de la UNAD., 57: 58-62.

Torres, J.A., Díaz, L. & Sánchez, F.J. (2009). Falling film reactor for methyl ester sulphonation with gaseous sulphur trioxide. Ingeniería e Investigación, 29 (3): 48–53.

Torres, J.A. (2012). Sulfonation/Sulfation processing technology for anionic surfactant manufactures. In: Advances in Chemical Engineering. Nawaz Z. and Naveed S. (eds.), pp. 269–294. Intech, Croatia.

license

How to Cite

Torres Ortega, A. J., & Morales Pedraza, N. (2011). Bio-Detergent oil derivative used frying. Publicaciones E Investigación, 5(1), 87-99. https://doi.org/10.22490/25394088.588

Download Citation

Almétricas

Metrics

Metrics Loading ...